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Organosilanes in Radical Chemistry: Principles, Methods and Applications
Chryssostomo Chatgilialoglu (Consiglio Nazionale della Ricerche)
In recent years silicon-centred radicals have played an important role in organic synthesis, polymer chemistry and material sciences. This book offers, for the first time, a description of silyl radicals within an interdisciplinary context, connecting structural characteristics and chemical properties to their application in different areas of chemistry. Silyl radicals have thoroughly penetrated areas as diverse as organic synthesis and material sciences, and this book surveys the most exciting aspects of their chemistry.

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Focusing on silyl radicals in the liquid phase, but including gas-phase data where appropriate, topics covered include:

· methods of formation, structural characteristics and thermodynamic data